I only see you doing a SELECT in both variants. If you want to make sure you don't sell more than you have in store (stock), you must decrease your stock in the same transaction you place the order. In PostgreSQL 9.1 you could use a data-modifying CTE for the job:
WITH u AS (
UPDATE product SET quant = quant - <put_order_quant_here>
WHERE product_id = <order_prod_id>
AND quant >= <put_order_quant_here>
RETURNING product_id, <put_order_quant_here> AS quant
)
INSERT INTO order_detail (order_id, product_id, quant)
SELECT <put_order_id_here>, product_id, quant
FROM u;
The UPDATE in the CTE only returns values if the product has sufficient stock. IN this case, the quantity is reduced in the same transaction, just before the order is placed.
Put all order-details into one transaction, if any of them fails to INSERT, ROLLBACK.
Possible deadlocks
One more piece of advice: this scenario could easily lead to deadlocks. Say, you have two orders coming in at the same time, both want product A and B. The first order starts by placing the order_detail on A, the second starts with B. Then the two transactions block each other out. Each of them would wait for the other to complete. A deadlock ensues.
In PostgreSQL a transaction will wait for some time when it is stalled by locks. Depending on your setting of deadlock_timeout (default is 1s, which I set to at least 5s on untroubled production servers), checks for a possible deadlock condition will be performed.
Once detected, one transaction will be aborted and report a deadlock exception. The other one can finish. Which one is hard to predict.
There is a simple way to avoid this kind of deadlocks: Always place your order_details in a consistent order. Like products ordered by product_id. This way, the above scenario can never happen.