CTE
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A CTE creates the table being used in memory, but is only valid for the specific query following it. When using recursion, this can be an effective structure, but bear in mind that it will need to be recreated everytime it's needed.
You might also consider here a table variable. This is used as a temp table is used, but is also in-memory only, but can be used multiple times without needing to be recreated every time. Also, if you need to persist a few records now, add a few more records after the next select, add a few more records after another op, then return just those handful of records, then this is a handy in-memory structure.
Temp Table
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A temp table is literally a table created on disk, just in a specific database that everyone knows can be deleted. It is the responsibility of a good dev to destroy those tables when they are no longer needed, but a DBA can also wipe them.
Temporary tables come in two variety: Local and global. In terms of MS Sql Server you use a #tableName designation for local, and ##tableName designation for global (note the use of a single or double # as the identifying characteristic).
Notice that with temp tables, as opposed to table variables or CTE, you can apply indexes and the like, as these are legitimately tables in the normal sense of the word.
Generally I would use temp tables for longer or larger queries, and CTEs or table variables if I had a small dataset already and wanted to just quickly script up a bit of code for something small.