You can also query this data with a select statement:
select *
from msdb.dbo.sysmail_profile p
join msdb.dbo.sysmail_profileaccount pa on p.profile_id = pa.profile_id
join msdb.dbo.sysmail_account a on pa.account_id = a.account_id
join msdb.dbo.sysmail_server s on a.account_id = s.account_id
If it is a migration that would require you to look this info up, I'd suggest the absurdly simple DBA Tools: Copy db MailDBA Tools: Copy db Mail.