I see it is available. Just can't find the right documentation to help me enable it.
From the docs, I entered the following command and got:
postgres=> select * from pg_available_extensions where name in ('plv8','plls','plcoffee');
name | default_version | installed_version | comment
----------+-----------------+-------------------+--------------------------------------------------
plcoffee | 2.3.8 | | PL/CoffeeScript (v8) trusted procedural language
plls | 2.3.8 | | PL/LiveScript (v8) trusted procedural language
plv8 | 2.3.8 | | PL/JavaScript (v8) trusted procedural language
(3 rows)
PLV8 looks to be available.