So why does Postgres 9.2 still show a sequential scan? I quote the Postgres Wiki:
Is "count(*)" much faster now?
A traditional complaint made of PostgreSQL, generally when comparing
it unfavourably with MySQL (at least when using the MyIsam storage
engine, which doesn't use MVCC) has been "count(*) is slow".
Index-only scans can be used to satisfy these queries without there
being any predicate to limit the number of rows returned, and without
forcing an index to be used by specifying that the tuples should be
ordered by an indexed column. However, in practice that isn't
particularly likely.
It is important to realise that the planner is concerned with
minimising the total cost of the query. With databases, the cost of
I/O typically dominates. For that reason, "count(*) without any
predicate" queries will only use an index-only scan if the index is
significantly smaller than its table. This typically only happens when
the table's row width is much wider than some indexes'.
Emphasis mine.
There is hardly anything to gain from an index scan here, as long as your talbe isn't bloated with more (big) columns.